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crown ether

noun

  1. chem a type of cyclic ether consisting of a ring of carbon and oxygen atoms, with two or more carbon atoms between each oxygen atom

“Collins English Dictionary — Complete & Unabridged” 2012 Digital Edition © William Collins Sons & Co. Ltd. 1979, 1986 © HarperCollins Publishers 1998, 2000, 2003, 2005, 2006, 2007, 2009, 2012


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Additionally, unlike the usual behavior of crown ether molecules in solution, these molecules did not trap the metal atom at the center of the crown ring.

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In summary, the team successfully demonstrated the growth of cobalt NCs by exploiting the trapping potential of two-dimensional crown ether molecules on a copper surface.

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The chemical behavior of the crown ether molecules deviated from typical interactions observed in solution, by trapping cobalt atoms at the edge, and not the center.

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To achieve high solubility in the bulky solvent, the team functionalised each cage with six crown ether groups.

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‘Usually, long or branched alky chains are employed to increase the solubility or lower the melting point of a larger molecule, but linear alkyl chains can penetrate into the cavities of adjacent molecules, resulting in non-porous liquids. James et al used a clever trick to solve this problem: they combined a porous crown-ether-decorated molecule with a crown ether.’

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