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unsubstituted

  • a word derived from substitute.
    substitute
    noun
    a person or thing acting or serving in place of another.

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Hence, unless the radical introduced be one which exercises a special attractive influence, substitution should take place in preference in the previously unsubstituted ring.

From Encyclopaedia Britannica, 11th Edition, Volume 6, Slice 1 "Châtelet" to "Chicago" by Various