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allylic
[uh-lil-ik]
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Jung, B. & Hoveyda, A. H. Site- and enantioselective formation of allene-bearing tertiary or quaternary carbon stereogenic centers through NHC–Cu-catalyzed allylic substitution.
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In the final step the allylic hydroperoxide undergoes an acid-catalysed Hock fragmentation and rearrangement to afford a ring-opened keto-aldehyde enol.
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