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empirical formula

American  

noun

Chemistry.
  1. a chemical formula indicating the elements of a compound and their relative proportions, as (CH 2 O) n .


empirical formula British  

noun

  1. a chemical formula indicating the proportion of each element present in a molecule Compare molecular formula structural formula

    C6H12O6 is the molecular formula of sucrose whereas CH2O is its empirical formula

  2. a formula or expression obtained from experimental data rather than theory

"Collins English Dictionary — Complete & Unabridged" 2012 Digital Edition © William Collins Sons & Co. Ltd. 1979, 1986 © HarperCollins Publishers 1998, 2000, 2003, 2005, 2006, 2007, 2009, 2012

empirical formula Scientific  
  1. A chemical formula that indicates the relative proportions of the elements in a molecule rather than the actual number of atoms of the elements. The empirical formula of a compound may be simpler than its molecular formula, which is a multiple of the empirical formula. For example, glucose has the molecular formula C 6 H 12 O 6 but the empirical formula CH 2 O.

  2. Compare molecular formula structural formula


Etymology

Origin of empirical formula

First recorded in 1820–30

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Example Sentences

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Consider as another example a sample of compound determined to contain 5.31 g Cl and 8.40 g O. Following the same approach yields a tentative empirical formula of:

From Textbooks • Feb. 14, 2019

In this case, dividing by the smallest subscript still leaves us with a decimal subscript in the empirical formula.

From Textbooks • Feb. 14, 2019

Coefficients for the tentative empirical formula are derived by dividing each molar amount by the lesser of the two:

From Textbooks • Feb. 14, 2019

The molecular formula is thus derived from the empirical formula by multiplying each of its subscripts by three:

From Textbooks • Feb. 14, 2019

The principal constituent of the crude material is the pure gutta, a hydrocarbon of the empirical formula C10H16.

From Encyclopaedia Britannica, 11th Edition, Volume 12, Slice 6 "Groups, Theory of" to "Gwyniad" by Various